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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Bromination of fluoroalkanes. Part 4.-Kinetics of thermal bromination of fluoroform and pentafluorethane
Journal:   Trans. Faraday Soc.
Volume:   64
Year:   1968
Reference type:   Journal article
Squib:   1968AMP/WHI2130

Reaction:   CF3CH2F + Br·HBr + CF3CHF
Reaction order:   2
Temperature:   403 - 591 K
Rate expression:   6.41x10-11 [cm3/molecule s] e-81565 [±816 J/mole]/RT
Uncertainty:   1.14999998
Bath gas:   CF3CH2F
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
403 1.72E-21
425 6.06E-21
450 2.18E-20
475 6.88E-20
500 1.93E-19
525 4.92E-19
550 1.15E-18
575 2.50E-18
591 3.96E-18