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Accessibility information
Author(s):   Barnard, J.A.; Cohen, A.
Title:   Reaction of methyl radicals with oxygen
Journal:   Trans. Faraday Soc.
Volume:   64
Page(s):   396 - 404
Year:   1968
Reference type:   Journal article
Squib:   1968BAR/COH396-404

Reaction:   Acetone + CH3O2·CH3OOH + CH3C(O)CH2(·)
Reaction order:   2
Reference reaction:   CH3O2·CH2O + ·OH
Reference reaction order:   2
Temperature:   573 - 773 K
Pressure:  0.13 bar
Rate expression:   1.3x106 e72170 [J/mole]/RT
Bath gas:   Acetone
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
573 4.93E12
575 4.68E12
600 2.49E12
625 1.40E12
650 8.19E11
675 5.00E11
700 3.16E11
725 2.06E11
750 1.38E11
773 9.79E10