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Accessibility information
Author(s):   Herron, J.T.; Huie, R.E.
Title:   Arrhenius parameters for the reactions of atomic nitrogen with some alefins and acetylenes
Journal:   J. Phys. Chem.
Volume:   72
Year:   1968
Reference type:   Journal article
Squib:   1968HER/HUI2538

Reaction:   C4H9C≡CH + N → Products
Reaction order:   2
Temperature:   320 - 550 K
Pressure:  3.33E-3 bar
Rate expression:   7.66x10-13 [cm3/molecule s] e-10227 [±8314472 J/mole]/RT
Uncertainty:   1.35000002
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
320 1.64E-14
325 1.74E-14
350 2.28E-14
375 2.88E-14
400 3.54E-14
425 4.24E-14
450 4.98E-14
475 5.75E-14
500 6.54E-14
525 7.35E-14
550 8.18E-14