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Accessibility information
Author(s):   Modica, A.P.; Sillers, S.J.
Title:   Experimental and theoretical kinetics of high-temperature fluorocarbon chemistry
Journal:   J. Chem. Phys.
Volume:   48
Page(s):   3283 - 3289
Year:   1968
Reference type:   Journal article
Squib:   1968MOD/SIL3283-3289

Reaction:   ·CF3 + ·CF3C2F6
Reaction order:   3
Temperature:   1700 - 3000 K
Pressure:  0.12 - 0.50 bar
Rate expression:   3.39x10-29 [cm6/molecule2 s] (T/298 K)0.50
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
1700 8.10E-29
1800 8.34E-29
1900 8.56E-29
2000 8.79E-29
2100 9.00E-29
2200 9.22E-29
2300 9.42E-29
2400 9.62E-29
2500 9.82E-29
2600 1.00E-28
2700 1.02E-28
2800 1.04E-28
2900 1.06E-28
3000 1.08E-28