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Accessibility information
Author(s):   Morris, E.R.; Thynne, J.C.J.
Title:   Reactions of radicals containing fluorine. Part 2.-Hydrogen and deuterium atom abstraction from methylamine and trideuteromethylamine by trifluoromethyl radicals
Journal:   Trans. Faraday Soc.
Volume:   64
Page(s):  
Year:   1968
Reference type:   Journal article
Squib:   1968MOR/THY2124

Reaction:   CH3NH2 + ·CF3 → Other Products + CHF3
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3 → C2F6
Temperature:   303 - 435 K
Pressure:  1.33E-2 - 4.93E-2 bar
Rate expression:   1.02x10-13 [cm3/molecule s] e-17544 [±1048 J/mole]/RT
Uncertainty:   1.45000005
Bath gas:   CF3I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
303 9.69E-17
325 1.55E-16
350 2.47E-16
375 3.69E-16
400 5.24E-16
425 7.15E-16
435 8.02E-16