Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Morris, E.R.; Thynne, J.C.J.
Title:   Reactions of radicals containing fluorine. Part 1.-Hydrogen and deuterium atom abstraction from trideuteromethanol by trifluoromethyl radicals
Journal:   Trans. Faraday Soc.
Volume:   64
Year:   1968
Reference type:   Journal article
Squib:   1968MOR/THY414

Reaction:   CD3OH + ·CF3 → CDF3 + CD2OH
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3C2F6
Temperature:   357 - 435 K
Pressure:  2.00E-2 - 4.40E-2 bar
Rate expression:   2.62x10-14 [cm3/molecule s] e-27687 [±2769 J/mole]/RT
Uncertainty:   1.70000005
Bath gas:   CF3I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
357 2.33E-18
375 3.65E-18
400 6.36E-18
425 1.04E-17
435 1.24E-17