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Accessibility information
Author(s):   Politanskii, S.F.; Shevchuk, U.V.
Title:   Thermal conversions of fluoromethanes. II. Pyrolysis of difluoromethane and trifluoromethane
Journal:   Kinet. Catal.
Volume:   9
Page(s):   411 - 417
Year:   1968
Reference type:   Journal article
Squib:   1968POL/SHE411-417

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1968POL/SHE411-417   CH2F2HF + ·CHF  1020 - 1320   8.91E12       2.94E05      1
  1968POL/SHE411-417   CH2=CF2 → Products  1020 - 1320   1.00E12       2.76E05      1
  1968POL/SHE411-417   CH2=CF2 + ·CHF → Adduct  1020 - 1320   31.10              2
  Reference reaction:  CH2F2 + ·CHFCH2=CF2 + HF 2
  1968POL/SHE411-417   CHF3·CF2 + HF  1020 - 1320   2.75E13       2.89E05      1

Search returned 4 records.