
Kinetics Database Resources
Simple Reaction Search
Search Reaction Database
Search Bibliographic Database
Set Unit Preferences
Feedback
Rate Our Products and Services
Help
Other Databases
NIST Standard Reference Data Program
NIST Chemistry Web Book
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
More...
Administrative Links
NIST home page
MML home page
Chemical Sciences Division
|
Author(s):
Pritchard, G.O.; Bryant, J.T.
Title:
The photolysis of 1,3-difluoro- and 1,1,3,3-tetrafluoroacetone at low pressure
Journal:
J. Phys. Chem.
Volume:
72
Page(s):
1603 - 1611
Year:
1968
Reference type:
Journal article
Squib:
1968PRI/BRY1603-1611
Reaction:
·CHF2 + ·CH2F → CH3F + ·CF2
Reaction order:
2
Reference reaction:
·CHF2 + ·CH2F → CH2FCHF2
Reference reaction order:
2
Temperature:
393 - 402
K
Pressure: 1.33E-4 - 4.80E-4 bar
Rate expression:
6.0x10-2
Bath gas:
Cyclopropane, 1,1,2,2-tetrafluoro-
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
|