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Accessibility information
Author(s):   Wilson, Wm.E., Jr.; O'Donovan, J.T.
Title:   Rate constants for the reaction of oxygen atoms with CH3Cl, CH3Br, and CF3H
Journal:   J. Chem. Phys.
Volume:   48
Year:   1968
Reference type:   Journal article
Squib:   1968WIL/ODO2829

Reaction:   CH3Cl + ·OH + ·CH2Cl
Reaction order:   2
Reference reaction:   CH4 + ·CH3 + ·OH
Reference reaction order:   2
Temperature:   353 - 949 K
Pressure:  1.33E-3 bar
Rate expression:   1.1 e3642 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
353 3.80E0
400 3.29E0
450 2.91E0
500 2.64E0
550 2.44E0
600 2.28E0
650 2.16E0
700 2.06E0
750 1.97E0
800 1.90E0
850 1.84E0
900 1.79E0
949 1.75E0