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Accessibility information
Author(s):   Bott, J.F.; Jacobs, T.A.
Title:   Shock-tube studies of sulfur hexafluoride
Journal:   J. Chem. Phys.
Volume:   50
Year:   1969
Reference type:   Journal article
Squib:   1969BOT/JAC3850

Reaction:   SF6SF5 + ·F
Reaction order:   1
Temperature:   1650 - 2050 K
Pressure:  0.13 - 30.40 bar
Rate expression:   8.91x1012 [s-1] e-317613 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1650 7.86E2
1675 1.11E3
1700 1.55E3
1725 2.15E3
1750 2.95E3
1775 4.01E3
1800 5.41E3
1825 7.24E3
1850 9.60E3
1875 1.26E4
1900 1.65E4
1925 2.15E4
1950 2.77E4
1975 3.55E4
2000 4.52E4
2025 5.72E4
2050 7.20E4