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Author(s):   Cadman, P.; Tilsley, G.M.; Trotman-Dickenson, A.F.
Title:   Reactions of trichlorosilyl radicals with n-propyl chloride, cyclopentyl chloride, and carbon tetrachloride
Journal:   J. Chem. Soc. A
Page(s):   1370 - 1372
Year:   1969
Reference type:   Journal article
Squib:   1969CAD/TIL1370-1372

Reaction:   CCl4 + SiCl3·CCl3 + SiCl4
Reaction order:   2
Reference reaction:   CH3Br + SiCl3·CH3 + Silane, bromotrichloro-
Reference reaction order:   2
Temperature:   353 - 553 K
Rate expression:   4.26x101±3.4 e14135 [±848 J/mole]/RT
Bath gas:   SiHCl3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
353 5.26E3
375 3.96E3
400 2.99E3
425 2.33E3
450 1.86E3
475 1.53E3
500 1.28E3
525 1.09E3
550 9.37E2
553 9.21E2