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Accessibility information
Author(s):   Castellano, E.; Schumacher, H.J.
Title:   Die Kinetik und der Mechanismus des photochemischen Ozonzerfalles im Licht der Wellenlange 313 mμ
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   65
Page(s):   62 - 85
Year:   1969
Reference type:   Journal article
Squib:   1969CAS/SCH62-85

Reaction:   O(1D) + O2O3
Reaction order:   2
Reference reaction:   O(1D) + O3O2 + O2
Reference reaction order:   2
Temperature:   247 - 298 K
Pressure:  2.00E-2 - 0.40 bar
Rate expression:   3.95x10-2 e4232 [J/mole]/RT
Bath gas:   O3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
247 3.10E-1
250 3.03E-1
275 2.51E-1
298 2.18E-1