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Title: Kinetics of gas-phase fluorination of halomethanes
Journal: Trans. Faraday Soc.
Volume: 65
Page(s):
Year: 1969
Reference type: Journal article
Squib: 1969FOO/MCA3005
Reaction:
n-C4H10 + ·F → n-C4H9 + HF
Reaction order:
2
Reference reaction:
CH3Cl + ·F → ·CH2Cl + HF
Reference reaction order:
2
Temperature:
209 - 291
K
Rate expression:
8.09x10-1±2.5x10-1 e4473 [±8314472 J/mole]/RT
Bath gas:
H2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 209 | 1.06E1 |
| 225 | 8.84E0 |
| 250 | 6.96E0 |
| 275 | 5.72E0 |
| 291 | 5.14E0 |