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Accessibility information
Author(s):   Foon, R.; McAskill, N.A.
Title:   Kinetics of gas-phase fluorination of halomethanes
Journal:   Trans. Faraday Soc.
Volume:   65
Year:   1969
Reference type:   Journal article
Squib:   1969FOO/MCA3005

Reaction:   CH3Cl + ·F·CH2Cl + HF
Reaction order:   2
Reference reaction:   CH2Cl2 + ·FCHCl2 + HF
Reference reaction order:   2
Temperature:   250 - 333 K
Rate expression:   7.91±3.6 e-3592 [±8314472 J/mole]/RT
Bath gas:   H2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
250 1.41E0
275 1.64E0
300 1.87E0
325 2.09E0
333 2.16E0