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Accessibility information
Author(s):   Gray, P.; Arthur, N.L.; Lloyd, A.C.
Title:   Attack of trifluoromethyl radicals on ammonia and ammonia-d3
Journal:   Trans. Faraday Soc.
Volume:   65
Page(s):   775 - 779
Year:   1969
Reference type:   Journal article
Squib:   1969GRA/ART775-779

Reaction:   ·CF3 + ND3 → CDF3 + ND2
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3C2F6
Temperature:   326 - 513 K
Pressure:  0.16 - 0.20 bar
Rate expression:   4.9x10-14 [cm3/molecule s] e-39078 [±1563 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   ND3
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
326 2.68E-20
350 7.21E-20
375 1.77E-19
400 3.86E-19
425 7.71E-19
450 1.43E-18
475 2.47E-18
500 4.05E-18
513 5.14E-18