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Accessibility information
Author(s):   Gray, P.; Leyshon, L.J.
Title:   Hydrogen abstraction from amides. Isotope effects, reactivity of different sites, and secondary effects in the reaction of methyl radicals with formamide and acetamide
Journal:   Trans. Faraday Soc.
Volume:   65
Year:   1969
Reference type:   Journal article
Squib:   1969GRA/LEY780

Reaction:   CH3CONH2 + CD3 → Other Products + CHD3
Reaction order:   2
Reference reaction:   CD3 + CD3C2D6
Temperature:   406 - 530 K
Pressure:  2.67E-2 - 4.00E-2 bar
Rate expression:   3.55x10-13 [cm3/molecule s] e-43318 [±433 J/mole]/RT
Uncertainty:   1.12
Bath gas:   CH3CONH2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
406 9.50E-19
425 1.69E-18
450 3.33E-18
475 6.13E-18
500 1.06E-17
525 1.74E-17
530 1.91E-17