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Accessibility information
Author(s):   Herron, J.T.; Huie, R.E.
Title:   Rates of reaction of atomic oxygen. II. Some C2 to C8 alkanes
Journal:   J. Phys. Chem.
Volume:   73
Year:   1969
Reference type:   Journal article
Squib:   1969HER/HUI3327

Reaction:   CH4 + ·CH3 + ·OH
Reaction order:   2
Temperature:   300 - 1000 K
Rate expression:   3.64x10-11 [cm3/molecule s] e-37083 [J/mole]/RT
Bath gas:   Sr
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.27E-17
350 1.06E-16
400 5.23E-16
450 1.80E-15
500 4.86E-15
550 1.09E-14
600 2.15E-14
650 3.81E-14
700 6.22E-14
750 9.51E-14
800 1.38E-13
850 1.91E-13
900 2.56E-13
950 3.33E-13
1000 4.20E-13