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Author(s):   Pritchard, G.O.; Perona, M.J.
Title:   Some hydrogen atom abstraction reactions of CF2H and CFH2 radicals, and the C-H bond dissociation energy in CF2H2
Journal:   Int. J. Chem. Kinet.
Volume:   1
Page(s):   509 - 525
Year:   1969
Reference type:   Journal article
Squib:   1969PRI/PER509-525

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1969PRI/PER509-525   CH4 + ·CHF2 → CH2F2 + ·CH3  497 - 626   1.83E-11       7.03E04      2
  1969PRI/PER509-525   C2H6 + ·CHF2 → CH2F2 + ·C2H5  432 - 625   6.76E-12       5.27E04      2
  1969PRI/PER509-525   iso-C4H10 + ·CHF2 → Other Products + CH2F2  445 - 568   2.24E-12       3.89E04      2
  1969PRI/PER509-525   1-C4H10 + ·CHF2 → Other Products + CH2F2  458 - 632   1.02E-11       4.77E04      2
  1969PRI/PER509-525   1-C4H10 + ·CH2F → Other Products + CH3F  450 - 559   2.19E-12       4.90E04      2
  1969PRI/PER509-525   (CHF2)2CO + ·CHF2 → CHF2C(O)CF2· + CH2F2  458 - 617   3.09E-12       5.31E04      2
  1969PRI/PER509-525   (CH2F)2CO + ·CH2F → CH3F + CH2FC(O)CHF·  410 - 562   1.51E-12       4.39E04      2
  1969PRI/PER509-525   H2 + ·CHF2 → CH2F2 + H·  500 - 635   1.07E-11       5.48E04      2
  1969PRI/PER509-525   ·CHF2 + ·CHF2 → CH2F2 + ·CF2  297 - 449   0.17           0.17  2
  Reference reaction:  ·CHF2 + ·CHF2 → CHF2CHF2 2
  1969PRI/PER509-525   ·CHF2 + D2 → CHDF2 + D  473 - 627   1.05E-11       6.11E04      2
Search returned 10 records.