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Accessibility information
Author(s):   Pritchard, G.O.; Perona, M.J.
Title:   Some hydrogen atom abstraction reactions of CF2H and CFH2 radicals, and the C-H bond dissociation energy in CF2H2
Journal:   Int. J. Chem. Kinet.
Volume:   1
Page(s):   509 - 525
Year:   1969
Reference type:   Journal article
Squib:   1969PRI/PER509-525

Reaction:   n-C4H10 + ·CHF2 → Other Products + CH2F2
Reaction order:   2
Reference reaction:   ·CHF2 + ·CHF2CHF2CHF2
Temperature:   458 - 632 K
Rate expression:   1.02x10-11 [cm3/molecule s] e-47725 [±477 J/mole]/RT
Bath gas:   (CHF2)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
458 3.70E-17
475 5.79E-17
500 1.06E-16
525 1.83E-16
550 3.01E-16
575 4.73E-16
600 7.17E-16
625 1.05E-15
632 1.16E-15