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Accessibility information
Author(s):   Tsang, W.
Title:   Thermal decomposition of 3,4-dimethylpentene-1,2,3,3-trimethylpentane, 3,3-dimethylpentane, and isobutylbenzene in a single pulse shock tube
Journal:   Int. J. Chem. Kinet.
Volume:   1
Year:   1969
Reference type:   Journal article
Squib:   1969TSA245

Reaction:   (CH3)2CHCH(CH3)CH=CH2iso-C3H7 + CH2=CHCHCH3
Reaction order:   1
Reference reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Temperature:   1030 - 1090 K
Pressure:  0.69 - 1.67 bar
Rate expression:   5.01x1015 [s-1] e-270220 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1030 9.92E1
1050 1.81E2
1075 3.72E2
1090 5.63E2