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Author(s):   Blauer, J.A.; McMath, H.G.; Jaye, F.C.; Engleman, V.S.
Title:   The kinetics of dissociation of chlorine pentafluoride
Journal:   J. Phys. Chem.
Volume:   74
Page(s):   1183 - 1188
Year:   1970
Reference type:   Journal article
Squib:   1970BLA/MCM1183-1188

Reaction:   Chlorine pentafluoride·F + ClF4
Reaction order:   1
Temperature:   520 - 1120 K
Pressure:  3.33E-3 - 0.16 bar
Rate expression:   1.0x1016 [s-1] e-181255 [±9063 J/mole]/RT
Uncertainty:   10.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
520 6.21E-3
550 6.11E-2
600 1.66E0
650 2.72E1
700 2.98E2
750 2.38E3
800 1.46E4
850 7.27E4
900 3.02E5
950 1.08E6
1000 3.41E6
1050 9.62E6
1100 2.47E7
1120 3.52E7