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Accessibility information
Author(s):   Cadman, P.; Day, M.; Kirk, A.W.; Trotman-Dickenson, A.F.
Title:   Activation energies for the elimination of hydrogen fluoride from alkyl fluorides obtained by the activated molecule and competitive shock-tube techniques
Journal:   J. Chem. Soc. Chem. Commun.
Page(s):   203 - 204
Year:   1970
Reference type:   Journal article
Squib:   1970CAD/DAY203-204

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Reference reaction:   C2H5ClC2H4 + HCl
Temperature:   1140 - 1510 K
Rate expression:   2.95x1013 [s-1] e-297658 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1140 6.78E-1
1150 8.91E-1
1175 1.73E0
1200 3.26E0
1225 5.99E0
1250 1.08E1
1275 1.89E1
1300 3.24E1
1325 5.44E1
1350 8.97E1
1375 1.45E2
1400 2.31E2
1425 3.62E2
1450 5.59E2
1475 8.49E2
1500 1.27E3
1510 1.49E3