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Author(s):   Cadman, P.; Dodwell, C.; Trotman-Dickenson, A.F.; White, A.J.
Title:   The kinetics of hydrogen abstraction by difluoroamino-radicals, from propionaldehyde, and n- and iso-butyraldehyde, and their acyl radical decompositions
Journal:   J. Chem. Soc. A
Year:   1970
Reference type:   Journal article
Squib:   1970CAD/DOD2371

Reaction:   CH3CH2COCO + ·C2H5
Reaction order:   1
Reference reaction:   NF2 + CH3CH2CO → C2H5C(O)NF2
Reference reaction order:   2
Temperature:   273 - 448 K
Pressure:  1.60E-3 - 3.96E-2 bar
Rate expression:   1.78x1022 [molecule/cm3] e-46478 [±931 J/mole]/RT
Uncertainty:   1.20000005
Bath gas:   C2H5CHO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
273 2.27E13
275 2.64E13
300 1.44E14
325 6.02E14
350 2.06E15
375 5.97E15
400 1.51E16
425 3.45E16
448 6.77E16