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Author(s):   Cadman, P.; Trotman-Dickenson, A.F.; White, A.J.
Title:   The kinetics of hydrogen abstraction by difluoroamino-radicals, from acetaldehyde, n- and iso-valeraldehyde, and their acyl radical decompositions
Journal:   J. Chem. Soc. A
Year:   1970
Reference type:   Journal article
Squib:   1970CAD/TRO3189

Reaction:   iso-C4H9CO· → CO + iso-C4H9
Reaction order:   1
Reference reaction:   NF2 + iso-C4H9CO· → Adduct
Temperature:   353 - 423 K
Pressure:  1.60E-3 - 4.39E-2 bar
Rate expression:   1.38x1012 [s-1] e-40575 [±406 J/mole]/RT
Uncertainty:   1.04999995
Bath gas:   3-Methylbutanal
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
353 1.37E6
375 3.08E6
400 6.94E6
423 1.35E7