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Accessibility information
Author(s):   Cadman, P.; Trotman-Dickenson, A.F.; White, A.J.
Title:   The kinetics of hydrogen abstraction by difluoroamino-radicals, from acetaldehyde, n- and iso-valeraldehyde, and their acyl radical decompositions
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1970
Reference type:   Journal article
Squib:   1970CAD/TRO3189

Reaction:   iso-C4H9CO· → CO + iso-C4H9
Reaction order:   1
Reference reaction:   NF2 + iso-C4H9CO· → Adduct
Reference reaction order:   2
Temperature:   353 - 423 K
Pressure:  1.60E-3 - 4.39E-2 bar
Rate expression:   8.31x1021 [molecule/cm3] e-40575 [±406 J/mole]/RT
Uncertainty:   1.04999995
Bath gas:   3-Methylbutanal
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Electron spin resonance (ESR or EPR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
353 8.24E15
375 1.85E16
400 4.18E16
423 8.12E16