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Author(s):   Davis, D.D.; Braun, W.; Bass, A.M.
Title:   Reactions of Cl2P3/2: Absolute rate constants for reaction with H2, CH4, C2H6, CH2Cl2, C2Cl4, and c-C6H12
Journal:   Int. J. Chem. Kinet.
Volume:   2
Page(s):   101 - 114
Year:   1970
Reference type:   Journal article
Squib:   1970DAV/BRA101-114

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1970DAV/BRA101-114   CH4 + ·Cl → ·CH3 + HCl  298   1.50E-13           1.50E-13  2
  1970DAV/BRA101-114   C2H6 + ·Cl → ·C2H5 + HCl  298   6.71E-11           6.71E-11  2
  1970DAV/BRA101-114   CH2Cl2 + ·Cl → CHCl2 + HCl  298   5.50E-13           5.50E-13  2
  1970DAV/BRA101-114   Cyclohexane + ·Cl → Cyclohexyl + HCl  298   2.01E-10           2.01E-10  2
  1970DAV/BRA101-114   C2Cl4 + ·Cl → C2Cl5  298   5.30E-12           5.30E-12  2
  1970DAV/BRA101-114   H2 + ·Cl → HCl + H·  298   1.40E-14           1.40E-14  2
Search returned 6 records.