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Accessibility information
Author(s):   Dean, A.M.; Kistiakowsky, G.B.
Title:   Oxidation of carbon monoxide/methane mixtures in shock waves
Journal:   J. Chem. Phys.
Volume:   54
Page(s):   1718 - 1725
Year:   1970
Reference type:   Journal article
Squib:   1970DEA/KIS1718-1725

Reaction:   CO + O2CO2 +
Reaction order:   2
Temperature:   1750 - 2580 K
Pressure:  2.00E-2 bar
Rate expression:   2.01x10-11 [cm3/molecule s] e-251097 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1750 6.43E-19
1800 1.04E-18
1850 1.63E-18
1900 2.51E-18
1950 3.78E-18
2000 5.56E-18
2050 8.04E-18
2100 1.14E-17
2150 1.59E-17
2200 2.19E-17
2250 2.98E-17
2300 3.99E-17
2350 5.27E-17
2400 6.89E-17
2450 8.91E-17
2500 1.14E-16
2550 1.44E-16
2580 1.66E-16