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Accessibility information
Author(s):   Dickey, L.C.; Firestone, R.F.
Title:   Radiolysis of chloroform vapor. Effects of phase on the arrhenius parameters of the hydrogen-atom abstraction reaction of dichloromethyl radicals with chloroform
Journal:   J. Phys. Chem.
Volume:   74
Year:   1970
Reference type:   Journal article
Squib:   1970DIC/FIR4310

Reaction:   CHCl3 + CHCl2CH2Cl2 + ·CCl3
Reaction order:   2
Reference reaction:   CHCl2 + CHCl2(CHCl2)2
Temperature:   352 - 373 K
Pressure:  6.35E-2 - 1.69 bar
Rate expression:   3.01x10-15 [cm3/molecule s] e-26773 [J/mole]/RT
Uncertainty:   2.0
Bath gas:   N2O
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Ultrasonics
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
352 3.20E-19
373 5.36E-19