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Author(s):   Furuyama, S.; Golden, D.M.; Benson, S.W.
Title:   Kinetic study of the gas-phase reaction c-C5H8 + I2 = c-C5H6 + 2HI. The heat of formation and the stabilization energy of the cyclopentenyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   2
Year:   1970
Reference type:   Journal article
Squib:   1970FUR/GOL93

Reaction:   HI + CyclopentenylCyclopentene + I
Reaction order:   2
Temperature:   451 - 556 K
Pressure:  8.27E-3 - 1.40E-2 bar
Rate expression:   1.66x10-12 [cm3/molecule s] e-4182 [±4182 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   Cyclopentene
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
451 5.44E-13
475 5.76E-13
500 6.07E-13
525 6.37E-13
550 6.65E-13
556 6.72E-13