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Accessibility information
Author(s):   Gibb, T.; Peters, M.J.; Tedder, J.M.; Walton, J.C.; Winton, K.D.R.
Title:   The orientation of free-radical addition to olefins
Journal:   J. Chem. Soc. Chem. Commun.
Page(s):  
Year:   1970
Reference type:   Journal article
Squib:   1970GIB/PET978

Reaction:   C2H4 + n-C3F7 → CF3CF2CF2CH2CH2
Reaction order:   2
Temperature:   331 - 423 K
Rate expression:   5.25x10-14 [cm3/molecule s] e-8398 [J/mole]/RT
Bath gas:   n-C3H7I
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
331 2.48E-15
350 2.93E-15
375 3.55E-15
400 4.20E-15
423 4.82E-15