Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Greiner, N.R.
Title:   Hydroxyl radical kinetics by kinetic spectroscopy. VI. Reactions with alkanes in the range 300-500°K
Journal:   J. Chem. Phys.
Volume:   53
Page(s):  
Year:   1970
Reference type:   Journal article
Squib:   1970GRE1070

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1970GRE1070   CH4 + ·OH·CH3 + H2O  301 - 492   5.50E-12       1.58E04      2
  1970GRE1070   C2H6 + ·OH·C2H5 + H2O  299 - 493   1.86E-11       1.02E04      2
  1970GRE1070   C3H8 + ·OH → Other Products + H2O  299 - 497   6.31E-12       5022      2
  1970GRE1070   C3H8 + ·OHiso-C3H7 + H2O  299 - 497   4.85E-12       3559      2
  1970GRE1070   C3H8 + ·OH1-C3H7 + H2O  299 - 497   6.13E-12       6843      2
  1970GRE1070   iso-C4H10 + ·OH → Other Products + H2O  297 - 498   3.47E-12       1605   1.82E-12  2
  1970GRE1070   iso-C4H10 + ·OHtert-C4H9 + H2O  297 - 498   2.09E-12       -798   2.89E-12  2
  1970GRE1070   iso-C4H10 + ·OHiso-C4H9 + H2O  297 - 498   9.22E-12       6843   5.82E-13  2
  1970GRE1070   (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O  300 - 498   2.24E-12       -2669      2
  1970GRE1070   (CH3)2CHCH(CH3)2 + ·OHH2O + (CH3)2CHC(·)(CH3)2  300 - 498   4.18E-12       -798      2
  1970GRE1070   1-C4H10 + ·OH → Other Products + H2O  298 - 497   9.33E-12       3783   2.03E-12  2
  1970GRE1070   1-C4H10 + ·OHsec-C4H9 + H2O  298 - 497   9.37E-12       3559   2.23E-12  2
  1970GRE1070   1-C4H10 + ·OH1-C4H9 + H2O  298 - 497   6.13E-12       6843   3.87E-13  2
  1970GRE1070   Cyclohexane + ·OHCyclohexyl + H2O  295 - 497   2.34E-11       2652   8.03E-12  2
  1970GRE1070   n-C8H18 + ·OH → Other Products + H2O  296 - 497   2.57E-11       2752   8.48E-12  2
  1970GRE1070   n-C8H18 + ·OH → 2-C8H17 + H2O  296 - 497   9.37E-12       3559   2.23E-12  2
  1970GRE1070   n-C8H18 + ·OH → 1-C8H17 + H2O  296 - 497   6.13E-12       6843   3.87E-13  2
  1970GRE1070   n-C8H18 + ·OHH2O + 4-C8H17  296 - 497   9.37E-12       3559   2.23E-12  2
  1970GRE1070   n-C8H18 + ·OHH2O + 3-C8H17  296 - 497   9.37E-12       3559   2.23E-12  2
  1970GRE1070   neo-C5H12 + ·OHNeopentyl + H2O  292 - 493   1.41E-11       7017   8.32E-13  2
  1970GRE1070   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  303 - 497   2.29E-12       -1372      2
  1970GRE1070   2,2,3-Trimethylbutane + ·OHH2O + (CH3)3C-C(·)(CH3)2  303 - 497   2.09E-12       -798      2
  1970GRE1070   2,2,3-Trimethylbutane + ·OHH2O + (CH3)3CCH(CH3)CH2·  303 - 497   6.13E-12       6843      2
  1970GRE1070   (CH3)2CHCH2C(CH3)3 + ·OH → Other Products + H2O  298 - 493   1.55E-11       3542   3.71E-12  2
  1970GRE1070   (CH3)3CC(CH3)3 + ·OHH2O + (CH3)3CC(CH3)2CH2  294 - 495   1.62E-11       6668   1.10E-12  2

Search returned 25 records.