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Accessibility information
Author(s):   Simmie, J.M.; Tschuikow-Roux, E.
Title:   Thermal decomposition of vinylidene fluoride behind reflected shock waves
Journal:   J. Chem. Soc. Chem. Commun.
Page(s):  
Year:   1970
Reference type:   Journal article
Squib:   1970SIM/TSC773

Reaction:   CH2=CF2 → Products
Reaction order:   1
Temperature:   1290 - 1480 K
Pressure:  4.40 bar
Rate expression:   1.26x1013 [s-1] e-335073 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1290 3.41E-1
1300 4.34E-1
1325 7.79E-1
1350 1.37E0
1375 2.35E0
1400 3.97E0
1425 6.58E0
1450 1.07E1
1475 1.72E1
1480 1.88E1