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Author(s):   Solly, R.K.; Golden, D.M.; Benson, S.W.
Title:   Kinetics of the gas-phase reaction of acetone with iodine: Heat of formation and stabilization energy of the acetonyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   2
Year:   1970
Reference type:   Journal article
Squib:   1970SOL/GOL11

Reaction:   (CH3)2CO + ICH3C(O)CH2(·) + HI
Reaction order:   2
Temperature:   613 - 703 K
Pressure:  2.53E-2 - 0.50 bar
Rate expression:   2.62x10-10 [cm3/molecule s] e-115571 [±9312 J/mole]/RT
Uncertainty:   5.0
Bath gas:   (CH3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
613 3.72E-20
625 5.76E-20
650 1.35E-19
675 2.99E-19
700 6.24E-19
703 6.79E-19