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Title: Kinetics and thermochemistry of the gas phase reaction of methyl ethyl ketone with iodine. I. The resonance energy of the methylacetonyl radical
Journal: Int. J. Chem. Kinet.
Volume: 2
Page(s): 381 - 391
Year: 1970
Reference type: Journal article
Squib: 1970SOL/GOL381-391
Reaction:
C2H5COCH3 + I → HI + CH3C(O)CH(·)CH3
Reaction order:
2
Temperature:
553 - 628
K
Pressure: 9.87E-3 - 0.40 bar
Rate expression:
9.47x10-11 [cm3/molecule s] e-92291 [±1837 J/mole]/RT
Uncertainty:
1.40999997
Bath gas:
C2H5COCH3
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 553 | 1.81E-19 |
| 575 | 3.91E-19 |
| 600 | 8.74E-19 |
| 625 | 1.83E-18 |
| 628 | 1.99E-18 |