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Accessibility information
Author(s):   Tsang, W.
Title:   Comparative rate single-pulse shock tube studies on the thermal decomposition of cyclohexene, 2,2,3-trimethylbutane, isopropyl bromide, and ethylcyclobutane
Journal:   Int. J. Chem. Kinet.
Volume:   2
Year:   1970
Reference type:   Journal article
Squib:   1970TSA311

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Reference reaction:   Cyclobutane, ethyl-C2H4 + 1-C4H8
Temperature:   950 - 1100 K
Pressure:  2.03 - 6.08 bar
Rate expression:   2.0x1015 [s-1] e-280198 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
950 7.85E-1
975 1.95E0
1000 4.63E0
1025 1.05E1
1050 2.30E1
1075 4.86E1
1100 9.90E1