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Title: Determination of the Elementary Reaction Rate Constants on the Basis of the Summary Values of the Rate Constant. Communication 2. Reactions of Oxygen Atoms with Oxygen-Containing Compounds
Journal: Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Volume: 20
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971AVR/KOL2700
Reaction:
CH3OH + O· → Other Products + ·OH
Reaction order:
2
Temperature:
330 - 505
K
Pressure: 1.87E-2 bar
Rate expression:
8.5x10-13 [cm3/molecule s] e-12971 [J/mole]/RT
Bath gas:
O2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 330 | 7.52E-15 |
| 350 | 9.86E-15 |
| 375 | 1.33E-14 |
| 400 | 1.72E-14 |
| 425 | 2.16E-14 |
| 450 | 2.65E-14 |
| 475 | 3.19E-14 |
| 500 | 3.75E-14 |
| 505 | 3.87E-14 |