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Author(s):   Cadman, P.; Day, M.; Trotman-Dickenson, A.F.
Title:   Static and shock tube pyrolyses of alkyl fluorides. Part III. The thermal decomposition of 1-chloro-2-fluoroethane, 1,1-difluoroethane, and 1,1,1-trifluoroethane
Journal:   J. Chem. Soc. A
Page(s):   1356 - 1360
Year:   1971
Reference type:   Journal article
Squib:   1971CAD/DAY1356-1360

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Reference reaction:   n-C3H7FCH3CH=CH2 + HF
Temperature:   1590 - 1680 K
Pressure:  1.07 - 1.20 bar
Rate expression:   6.31x1013 [s-1] e-308467 [±18458 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1590 4.64E3
1600 5.37E3
1625 7.67E3
1650 1.08E4
1675 1.52E4
1680 1.62E4