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Author(s):   Cadman, P.; Dodwell, C.; White, A.J.
Title:   Kinetics of the hydrogen abstraction from propane, n-butane, isobutane, and cyclopentane by difluoroamino-radicals
Journal:   J. Chem. Soc. A
Year:   1971
Reference type:   Journal article
Squib:   1971CAD/DOD2967

Reaction:   n-C4H10 + NF2 → Other Products + HNF2
Reaction order:   2
Temperature:   374 - 447 K
Pressure:  1.47E-2 - 0.16 bar
Rate expression:   3.24x10-12 [cm3/molecule s] e-103099 [±1031 J/mole]/RT
Uncertainty:   1.54999995
Bath gas:   n-C4H10
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
374 1.29E-26
375 1.41E-26
400 1.11E-25
425 6.90E-25
447 2.90E-24