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Author(s):   Cadman, P.; Trotman-Dickenson, A.F.; White, A.J.
Title:   Kinetics and Pressure-Dependence of the t-Butoxyl Radical Decomposition
Journal:   J. Chem. Soc. A
Year:   1971
Reference type:   Journal article
Squib:   1971CAD/TRO2296

Reaction:   (CH3)3CO → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   373 - 423 K
Pressure:  3.11E-2 - 0.46 bar
Rate expression:   2.34x1013 [s-1] e-70174 [±6319 J/mole]/RT
Uncertainty:   5.0
Bath gas:   C3H8
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
373 3.49E3
375 3.93E3
400 1.61E4
423 5.06E4