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Author(s):   Jackson, P.C.; Silverwood, R.; Thomas, J.H.
Title:   Gas-phase reaction between trifluoroacetaldehyde and nitrogen dioxide
Journal:   Trans. Faraday Soc.
Volume:   67
Year:   1971
Reference type:   Journal article
Squib:   1971JAC/SIL3250

Reaction:   CF3C(O)CO + ·CF3
Reaction order:   1
Reference reaction:   CF3C(O) + NO2NO + CF3C(O)O
Reference reaction order:   2
Temperature:   533 - 583 K
Pressure:  3.07E-2 - 3.33E-2 bar
Rate expression:   3.8x1021 [molecule/cm3] e-39826 [±8314472 J/mole]/RT
Uncertainty:   1.48000002
Bath gas:   CF3CHO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
533 4.75E17
550 6.27E17
575 9.16E17
583 1.03E18