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Accessibility information
Author(s):   Jaffe, S.
Title:   Some Reactions of Nitrogen Dioxide with Olefins
Journal:   Chem. React. Urban Atmos. Proc. Symp. 1969
Year:   1971
Reference type:   Journal article
Squib:   1971JAF103

Reaction:   CH3CHO + NO2CH3CO + HNO2
Reaction order:   2
Temperature:   298 - 373 K
Pressure:  1.01 bar
Rate expression:   2.62x10-19 [cm3/molecule s] e-28851 [J/mole]/RT
Uncertainty:   1.39999998
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.30E-24
300 2.49E-24
325 6.05E-24
350 1.30E-23
373 2.39E-23