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Accessibility information
Author(s):   Kerr, J.A.; Timlin, D.M.
Title:   Hydrogen abstraction reactions from organosilicon compounds. The reactions of fluoromethyl radicals with trichlorosilane. The photolyses of di- and tetrafluoroacetone
Journal:   Int. J. Chem. Kinet.
Volume:   3
Page(s):   1 - 14
Year:   1971
Reference type:   Journal article
Squib:   1971KER/TIM1-14

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1971KER/TIM1-14   ·CHF2 + ·CHF2CH2F2 + ·CF2  300 - 400   0.13              2
  Reference reaction:  ·CHF2 + ·CHF2CHF2CHF2 2
  1971KER/TIM1-14   ·CHF2 + SiHCl3CH2F2 + SiCl3  334 - 442   3.49E-13       2.85E04      2
  1971KER/TIM1-14   ·CH2F + SiHCl3CH3F + SiCl3  335 - 443   1.03E-13       2.54E04      2

Search returned 3 records.