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Author(s):   Kerr, J.A.; Timlin, D.M.
Title:   Hydrogen abstraction reactions from organosilicon compounds. The reactions of fluoromethyl radicals with trichlorosilane. The photolyses of di- and tetrafluoroacetone
Journal:   Int. J. Chem. Kinet.
Volume:   3
Page(s):   1 - 14
Year:   1971
Reference type:   Journal article
Squib:   1971KER/TIM1-14

Reaction:   ·CHF2 + ·CHF2CH2F2 + ·CF2
Reaction order:   2
Reference reaction:   ·CHF2 + ·CHF2CHF2CHF2
Reference reaction order:   2
Temperature:   300 - 400 K
Pressure:  1.15E-2 - 5.20E-2 bar
Rate expression:   1.3x10-1±1.0x10-2
Bath gas:   (CHF2)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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