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Accessibility information
Author(s):   Morris, E.D., Jr.; Niki, H.
Title:   Reactivity of Hydroxyl Radicals with Olefins
Journal:   J. Phys. Chem.
Volume:   75
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971MOR/NIK3640

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1971MOR/NIK3640   CH2O + ·OHHCO + H2O  300   0.90              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   C2H4 + ·OH → Products  300   0.10              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   CH3CHO + ·OH → Products  300   0.90              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   1-C4H10 + ·OH → Other Products + H2O  300   0.24              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   1-C4H8 + ·OH → Products  300   2.40              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   1-C5H10 + ·OH → Products  300   2.50              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   iso-C4H8 + ·OH → Products  300   3.80              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   C2H5CHO + ·OH → Products  300   1.80              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   (CH3)2C=CHCH3 + ·OH → Products  300   7.00              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   C2H5C(CH3)=CH2 + ·OH → Products  300   5.30              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   (CH3)2C=C(CH3)2 + ·OH → Products  300   8.99              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   (Z)-2-C4H8 + ·OH → Products  300   3.60              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   (E)-2-C4H8 + ·OH → Products  300   4.20              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   2-(Z)-C5H10 + ·OH → Products  300   5.30              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1971MOR/NIK3640   CD3CD=CD2 + ·OH → Products  300   1.10              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2

Search returned 15 records.