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Author(s):   O'Neal, H.E.; Pavlou, S.; Lubin, T.; Ring, M.A.; Batt, L.
Title:   Primary and secondary rate processes in the acetone-silane photochemical system
Journal:   J. Phys. Chem.
Volume:   75
Year:   1971
Reference type:   Journal article
Squib:   1971ONE/PAV3945

Reaction:   (CH3)2C(OH) + SiH4iso-C3H7OH + SiH3
Reaction order:   2
Temperature:   298 - 373 K
Rate expression:   9.33x10-13 [cm3/molecule s] e-37665 [±4141 J/mole]/RT
Bath gas:   (CH3)2CO
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.33E-19
300 2.58E-19
325 8.25E-19
350 2.23E-18
373 4.96E-18