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Accessibility information
Author(s):   Quick, L.M.; Whittle, E.
Title:   Reactions of Trifluoromethyl radicals with organic halides. Part 6.-Bromo- and fluoro-bromoethanes
Journal:   Trans. Faraday Soc.
Volume:   67
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971QUI/WHI1727

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1971QUI/WHI1727   C2H6 + ·CF3CHF3 + ·C2H5  295 - 528   1.66E-12       3.48E04   1.34E-18  2
  1971QUI/WHI1727   C2H5Br + ·CF3CHF3 + CH3CHBr  295 - 494   1.99E-14       2.18E04   3.03E-18  2
  1971QUI/WHI1727   C2H5Br + ·CF3CF3Br + ·C2H5  295 - 494   3.55E-14       2.92E04   2.72E-19  2
  1971QUI/WHI1727   CH2BrCH2Br + ·CF3 → Other Products + CHF3  297 - 493   8.92E-14       2.59E04   2.62E-18  2
  1971QUI/WHI1727   CH2BrCH2Br + ·CF3CF3Br + CH3CHBr  297 - 493   1.99E-13       3.23E04   4.27E-19  2
  1971QUI/WHI1727   CH2BrCH2Cl + ·CF3 → Other Products + CHF3  294 - 471   4.37E-13       3.23E04   9.36E-19  2
  1971QUI/WHI1727   CH2BrCH2Cl + ·CF3CF3Br + CH2CH2Cl  294 - 471   1.66E-13       3.00E04   9.10E-19  2
  1971QUI/WHI1727   C2H5F + ·CF3CHF3 + CH3C(·)HF  305 - 459   1.59E-12       3.44E04      2
  1971QUI/WHI1727   CHF2CBrF2 + ·CF3CHF3 + CF2BrCF2  298 - 492   1.11E-13       2.89E04   9.76E-19  2
  1971QUI/WHI1727   CHF2CBrF2 + ·CF3CF3Br + CHF2CF2  298 - 492   2.14E-13       3.40E04   2.35E-19  2
  1971QUI/WHI1727   C2F5Br + ·CF3CF3Br + C2F5  409 - 527   7.95E-12       5.31E04      2
  1971QUI/WHI1727   CH3CBrF2 + ·CF3CHF3 + ·CH2CBrF2  391 - 525   1.51E-14       3.10E04      2
  1971QUI/WHI1727   CH3CBrF2 + ·CF3CF3Br + CH3CF2  391 - 525   2.24E-12       4.38E04      2
  1971QUI/WHI1727   CF3CBrH2 + ·CF3 → Other Products + CHF3  405 - 548   6.61E-14       3.26E04      2
  1971QUI/WHI1727   CF3CBrH2 + ·CF3CF3Br + CF3CH2  405 - 548   4.78E-13       4.39E04      2
  1971QUI/WHI1727   CH3CHBr2 + ·CF3 → Other Products + CHF3  301 - 472   6.31E-14       2.20E04      2
  1971QUI/WHI1727   CH3CHBr2 + ·CF3CF3Br + CH3CHBr  301 - 472   5.50E-13       2.85E04      2
  1971QUI/WHI1727   CHBrF2 + ·CF3CHF3 + CBrF2  394 - 492   9.33E-13       4.51E04      2
  1971QUI/WHI1727   CHBrF2 + ·CF3CF3Br + ·CHF2  394 - 492   9.33E-13       4.46E04      2

Search returned 19 records.