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Accessibility information
Author(s):   Quick, L.M.; Whittle, E.
Title:   Reactions of Trifluoromethyl radicals with organic halides. Part 6.-Bromo- and fluoro-bromoethanes
Journal:   Trans. Faraday Soc.
Volume:   67
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971QUI/WHI1727

Reaction:   CF3CBrH2 + ·CF3 → Other Products + CHF3
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3 → C2F6
Temperature:   405 - 548 K
Pressure:  6.67E-2 bar
Rate expression:   6.61x10-14 [cm3/molecule s] e-32593 [±8314472 J/mole]/RT
Uncertainty:   1.12
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
405 4.14E-18
425 6.52E-18
450 1.09E-17
475 1.72E-17
500 2.60E-17
525 3.78E-17
548 5.17E-17