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Author(s):   Strausz, O.P.; O'Callaghan, W.B.; Lown, E.M.; Gunning, H.E.
Title:   Reactions of Sulfur Atoms. XII. Arrhenius Parameters for the Addition to Olefins and Acetylenes
Journal:   J. Am. Chem. Soc.
Volume:   93
Year:   1971
Reference type:   Journal article
Squib:   1971STR/OCA559

Reaction:   (CH3)2C=CHCH3 + SThiirane, trimethyl-
Reaction order:   2
Reference reaction:   C2H4 + SThiirane
Reference reaction order:   2
Temperature:   298 - 450 K
Pressure:  0.27 bar
Rate expression:   5.11x10-1 e12638 [J/mole]/RT
Bath gas:   CO2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 8.39E1
300 8.11E1
325 5.49E1
350 3.93E1
375 2.94E1
400 2.28E1
425 1.83E1
450 1.50E1