Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Strausz, O.P.; O'Callaghan, W.B.; Lown, E.M.; Gunning, H.E.
Title:   Reactions of Sulfur Atoms. XII. Arrhenius Parameters for the Addition to Olefins and Acetylenes
Journal:   J. Am. Chem. Soc.
Volume:   93
Year:   1971
Reference type:   Journal article
Squib:   1971STR/OCA559

Reaction:   CH2=CHCl + S → Adduct
Reaction order:   2
Reference reaction:   C2H4 + SThiirane
Reference reaction order:   2
Temperature:   298 - 450 K
Pressure:  0.27 bar
Rate expression:   3.4 e-2178 [J/mole]/RT
Bath gas:   CO2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.41E0
300 1.42E0
325 1.52E0
350 1.61E0
375 1.69E0
400 1.77E0
425 1.84E0
450 1.90E0