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Accessibility information
Author(s):   Tschuikow-Roux, E.; Quiring, W.J.
Title:   Kinetics of the thermally induced dehydrofluorination of 1,1,1-trifluoroethane in shock waves
Journal:   J. Phys. Chem.
Volume:   75
Page(s):   295 - 300
Year:   1971
Reference type:   Journal article
Squib:   1971TSC/QUI295-300

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Temperature:   1080 - 1310 K
Pressure:  3.20 - 4.53 bar
Rate expression:   1.0x1014 [s-1] e-287681 [±8647 J/mole]/RT
Uncertainty:   2.50999999
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1080 1.22E0
1100 2.19E0
1125 4.40E0
1150 8.58E0
1175 1.63E1
1200 3.00E1
1225 5.41E1
1250 9.52E1
1275 1.64E2
1300 2.76E2
1310 3.38E2